Identification

Title

Decoupling peroxyacetyl nitrate from ozone in Chinese outflows observed at Gosan Climate Observatory

Abstract

We measured peroxyacetyl nitrate (PAN) and other reactive species such as O3, NO2, CO, and SO2 with aerosols including mass, organic carbon (OC), and elemental carbon (EC) in PM2.5 and K+ in PM1.0 at Gosan Climate Observatory in Korea (33.17◦ N, 126.10◦ E) during 19 October - 6 November 2010. PAN was determined through fast gas chromatography with luminol chemiluminescence detection at 425 nm every 2 min. The PAN mixing ratios ranged from 0.1 (detection limit) to 2.4 ppbv with a mean of 0.6 ppbv. For all measurements, PAN was unusually better correlated with PM2.5 (Pearson correlation coefficient, γ = 0.79) than with O3 (γ = 0.67). In particular, the O3 level was highly elevated with SO2 at midnight, along with a typical midday peak when air was transported rapidly from the Beijing areas. The PAN enhancement was most noticeable during the occurrence of haze under stagnant conditions. In Chinese out-flows slowly transported over the Yellow Sea, PAN gradually increased up to 2.4 ppbv at night, in excellent correlation with a concentration increase in PM2.5 OC and EC, PM2.5 mass, and PM1.0 K +. The high K+ concentration and OC / EC ratio indicated that the air mass was impacted by biomass combustion. This study highlights PAN decoupling with O3 in Chinese outflows and suggests PAN as a useful indicator for diagnosing continental outflows and assessing their perturbation of regional air quality in northeast Asia.

Resource type

document

Resource locator

Unique resource identifier

code

http://n2t.net/ark:/85065/d7dz0btd

codeSpace

Dataset language

eng

Spatial reference system

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Classification of spatial data and services

Topic category

geoscientificInformation

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Text

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title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

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publication

effective date

2017-09-08T00:00:00Z

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Conformity

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None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

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