Identification

Title

Evaluation of the use of a commercially available cavity ringdown absorption spectrometer for measuring NO2 in flight, and observations over the Mid-Atlantic States, during DISCOVER-AQ

Abstract

Real time, atmospheric NO2 column profiles over the Mid-Atlantic states, during the July 2011 National Aeronautics and Space Administration (NASA) Deriving Information on Surface Conditions from Column and Vertically Resolved Observations to Air Quality (DISCOVER AQ) flight campaign, demonstrated that a cavity ring down spectrometer with a light emitting diode light source (LED-CRD) is a suitable technique for detecting NO2 in the boundary layer (BL) and lower free troposphere (LFT). Results from a side-by-side flight between a NASA P3 aircraft and a University of Maryland (UMD) Cessna 402B aircraft show that NO2 concentrations in ambient air from 0.08 nmol /mol (or ppbv) to 1.3 nmol/mol were consistent with NO2 measurements obtained via laser induced fluorescence (LIF) and photolysis followed by NO chemiluminescence (P-CL). The current LED-CRD, commercially available by Los Gatos Research (LGR), includes the modifications added by Castellanos et al. (Rev. Sci. Instrum. 80:113107, 2009) to compensate for baseline drift and humidity through built in zeroing and drying. Because of laser instability in the initial instrument, the laser light source in the Castellanos et al. (Rev. Sci. Instrum. 80:113107, 2009) instrument has been replaced with a light emitting diode. Six independent calibrations demonstrated the instrument's linearity up through 150 nmol/mol NO2 and excellent stability in calibration coefficient of 1.26 (+/- 3.7 %). The instrument detection limit is 80 pmol/mol. Aircraft measurements over the Mid-Atlantic are included showing horizontal and vertical distributions of NO2 during air quality episodes. During 23 research flights, NO2 profiles were measured west and generally upwind of the Baltimore/Washington, D.C. area in the morning and east (generally downwind) of the metropolitan region in the afternoon. Column contents (surface to 2,500 m altitude) were remarkably similar (a parts per thousand 3 x 10(15) molecules/cm(2)) indicating that NO2 is widely distributed over the eastern US contributing to the regional (spatial scales of approximately1000 km) nature of smog events.

Resource type

document

Resource locator

Unique resource identifier

code

http://n2t.net/ark:/85065/d7xk8ghx

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

End position

Dataset reference date

date type

publication

effective date

2015-09-01T00:00:00Z

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact